Search results for "dibutyl phosphate"

showing 3 items of 3 documents

Non-ideal mixing behavior in dibutyl phosphate-propylamine binary liquids: Dielectric and nuclear magnetic resonance investigations

2021

Abstract Owing to the amphiphilic nature of their constituent molecules, binary mixtures of pure liquid surfactants are usually characterized by enhanced nano-segregation and thus can exhibit interesting transport properties and complex macroscopic behavior. In this ambit it was recently shown by Turco Liveri et al. (J. Mol. Liq. 263 (2018) 274–281) at room temperature that mixtures of short aliphatic chains compounds, such as dibutyl phosphate (DBP) and n-propylamine (PA) liquids, due to their ability to allow for phosphate-to-amine proton transfer, display ionic liquid–like behavior with composition-dependent enhanced conductivity, viscosity, and magnetically-induced birefringence. To und…

Materials scienceProtonn-propyl amine; Dibutyl phosphate; Liquid mixtures; Self-assembly; Decoupling of dynamical processes; Ionic liquidsIonic bondingPropylamineDielectricConductivityCondensed Matter PhysicsAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsDielectric spectroscopychemistry.chemical_compoundViscosityNuclear magnetic resonancechemistryMaterials ChemistryMoleculePhysical and Theoretical ChemistrySpectroscopy
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CCDC 824722: Experimental Crystal Structure Determination

2012

Related Article: L.Lopez-Banet, M.D.Santana, G.Garcia, J.Perez, L.Garcia, L.Lezama, M.Liu|2012|Polyhedron|31|575|doi:10.1016/j.poly.2011.10.014

Space GroupCrystallographytriaqua-(hydrogen tris(35-dimethyl-1H-pyrazol-1-yl)borate)-nickel(ii) dibutyl phosphate hemihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Molecular association of small amphiphiles: Origin of ionic liquid properties in dibutyl phosphate/propylamine binary mixtures

2018

Abstract Binary mixtures of liquid surfactants, owing to the amphiphilic nature of the molecules involved, can exhibit nano-segregation and peculiar transport properties. The amphiphilicity, and consequently the resulting self-assembly, can be tuned by changing the length of the alkyl chains and the nature of the polar head group. So, in the present study, the structural and dynamic properties of dibutyl phosphate/propylamine liquid mixtures at various compositions have been investigated by Wide Angle X-ray Scattering (WAXS), FT-IR, rheometry and dielectric spectroscopy in order to study the intermolecular association taking place when alkylphosphates and alkylamines with a small apolar par…

Steric effectspropylaminePropylamine02 engineering and technologyDielectric010402 general chemistry01 natural sciencesionic liquidschemistry.chemical_compoundMaterials ChemistryMoleculePhysical and Theoretical ChemistrySpectroscopyAlkylchemistry.chemical_classificationamphiphilesIntermolecular forceself-assembly021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic MaterialsDielectric spectroscopychemistryChemical physicsdibutyl phosphateIonic liquid0210 nano-technology
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